David, Unfortunatley, my thermostat is difficult to get at as it's between the Fan and Calorifier. I will assume that whoever did it like this, set it at a sensible temperature.
I can set the temperature of the water coming out of the taps by using the black knob(DUCO), on the calorifier(see below). This is basicaly a valve which mixes hot & cold water. Turn it anti-clockwise to increase the hot water, clockwise to increase the cold water. I have included this paragrah and picture in the hope it may help someone else who gets confused.