Voltage is not the main issue when converting to lithium. Lead acid batteries of any type, have a much higher Internal resistance then lithium, and self limit charge current. In a typical motor home set up this will, be in the region of 10 to 20 amps. A lithium battery, without any current limiting control, could take 50 to 100 amps from the alternator.
Typical alternator voltage will be 14.2 to 14.4 volts, unless you have the later Euro 6 start stop smart alternator.
Regarding current output of the alternator, from 07 onwards its a 150 or 180 or 200 amp rated, 99 to 06 is 90 amp rated. Output at engine idle speed will be around 70% of maximum.
There is considerable mis information about charging lithium batteries, even from the battery suppliers and so called lithium chargers. Any charger with 'target' charge voltage from 13.8 volts to 14.6 volts will charge. Ideal is 14.0 or 14.2 volts. Absorbtion period should be short, less than1 hour. Float volts no more than 13.5 volts.
Unlike lead acid batteries lithium batteries dont have to be kept 'full'. In fact keeping the fully charged lithium battery at voltages over 13.5 volts , for long periods, will reduce service life.